THERMOPLASTIC STARCH BASED POLYMER BLENDS: SYNTHESIS, CHARACTERISATION AND ANALYSIS OF STABILITY
DOI:
https://doi.org/10.29121/shodhkosh.v5.i6.2024.3998Keywords:
Polymer Blends, Soil Bio-Degradbility, Cassava Starch, Water Uptake PercentageAbstract [English]
In the present work, thermoplastic starch from cassava starch was grafted with epoxy derived from castor oil polyol. Fresh starch, prepared from cassava root tuber was polymerised and blended with epoxy in different compositions leading to variations in properties. The synthesized polymer blends could be filled or reinforced with nano-silica for effective functionality by eco-friendly means. The synthesized blends were characterized using FT-IR, Scanning Electron Microscope, EDAX and the water uptake percentage and soil bio-degradability were studied. Further, mechanical and thermal stability of the blends were characterised. With further developments, these starch-based nanocomposites can be expected to replace conventional polymers for variety of applications.
References
Rhim J W and Ng PK. Natural biopolymer-based nanocomposite films for packaging applications. Crit Rev Food Sci Nutra 2007; 47(4): 411–433. DOI: https://doi.org/10.1080/10408390600846366
Zhang J F and Sun X Z. Mechanical properties of PLA/ starch composites compatibilized by maleic anhydride. Biomacromolecules 2004; 5: 1446–1451. DOI: https://doi.org/10.1021/bm0400022
Menna PL, Vinay , Goel A, et al. Packaging material and need of biodegradable polymers: a review. Int J App Res 2017; 3(7): 886–896.
Araujo MA, Cunha A and Mota M. Enzymatic degradation of starch-based thermoplastic compounds used in protheses: identification of the degradation products in solution. Biomaterials 2004; 25: 2687–2693. DOI: https://doi.org/10.1016/j.biomaterials.2003.09.093
Walenta E, Fink HP, Weigel P, et al. Structure-property relationships of extruded starch, 2 extrusion products from native starch. Micromole Mater Eng 2008; 286(8): 462–471. DOI: https://doi.org/10.1002/1439-2054(200108)286:8<462::AID-MAME462>3.3.CO;2-1
OEF Mohammed, Al Mustafa, BE Mohamed, GJ Fadimu, IA Mohammed Ahmed, Effect of pepsin and SO2 treatments on the yield, physicochemical, morphological, and functional properties of pearl millet starch. Journal of Food Measurement and Characterisation 2021; 15 (1179-1189). DOI: https://doi.org/10.1007/s11694-020-00714-8
Zhu, J.; Gao, W.; wang, B.; Kang, X.; Liu, P.; Cui, B.; El-Aty, A.M.A. Preparation and evaluation of starch based extrusion-blown nanocomposites films incorporated with nano-ZnO and nano-SiO2. Int. J. Biol. Macromol. 2021, 183, 1371-1378. DOI: https://doi.org/10.1016/j.ijbiomac.2021.05.118
Zuzanna Żołek-Tryznowska, Arkadiusz Jeznach, Ewa Bednarczyk, Tomasz Murawski, Katarzyna Piłczyńska, Szymon Sikora, Mariusz Tryznowski, Effect of hydrophobic nano-silica content on the surface properties of corn-starch films,Industrial Crops and Products, 214, 2024, 118582, https://doi.org/10.1016/j.indcrop.2024.118582. DOI: https://doi.org/10.1016/j.indcrop.2024.118582
Braich, Amandeep & Kaur, Gurkirat. (2022). Oxide-Based Nanocomposites for Food Packaging Application. Nanotechnology Interventions in Food Packaging and Shelf Life (125-156) https://doi.org/10.1201/9781003207641-8. DOI: https://doi.org/10.1201/9781003207641-8
X. Zhao, K. Cornish, Y. Vodovotz, Narrowing the gap for bioplastic use in food packaging: an update, Environ. Sci. Technol., 54 (8) (2020), pp. 4712-4732. DOI: https://doi.org/10.1021/acs.est.9b03755
S. Kirar, D. Mohne, M. Singh, V. Sagar, A. Bhise, S. Goswami, J. Bhaumik, Eco-friendly lignin nanocomposite films as advanced UV protective and antimicrobial sustainable packaging materials. Sustain. Mater. Technol., 40 (2024). DOI: https://doi.org/10.1016/j.susmat.2024.e00864
J. Kim, J. Bang, S. Park, M. Jung, S. Jung, H. Yun, J.-H. Kim, I.-G. Choi, H.W. Kwak, Enhanced barrier properties of biodegradable PBAT/acetylated lignin films, Sustain. Mater. Technol., 37 (2023). DOI: https://doi.org/10.1016/j.susmat.2023.e00686
R. Priyadarshi, S. Roy, T. Ghosh, D. Biswas, J.-W. Rhim, Antimicrobial nanofillers reinforced biopolymer composite films for active food packaging applications-a review. Sustain. Mater. Technol., 32 (2022). DOI: https://doi.org/10.1016/j.susmat.2021.e00353
R. Priyadarshi, S.-M. Kim, J.-W. Rhim, Carboxymethyl cellulose-based multifunctional film combined with zinc oxide nanoparticles and grape seed extract for the preservation of high-fat meat products. Sustain. Mater. Technol., 29 (2021). DOI: https://doi.org/10.1016/j.susmat.2021.e00325
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 Benlin Giftna J V, Begila David S

This work is licensed under a Creative Commons Attribution 4.0 International License.
With the licence CC-BY, authors retain the copyright, allowing anyone to download, reuse, re-print, modify, distribute, and/or copy their contribution. The work must be properly attributed to its author.
It is not necessary to ask for further permission from the author or journal board.
This journal provides immediate open access to its content on the principle that making research freely available to the public supports a greater global exchange of knowledge.
 
							 
			
		 
			 
			 
				













 
  
  
  
  
 