COMPARATIVE STUDY USING CFD OF COUNTER-CURRENT AND CO-CURRENT HYDROTREATING REACTORS USING JATROPHA CURCAS L VEGETABLE OIL
DOI:
https://doi.org/10.29121/ijoest.v8.i5.2024.635Keywords:
Countercurrent reactor, cocurrent reactor, CFD, BiofuelsAbstract
In this work, mathematical modeling and CFD simulation of two countercurrent and cocurrent hydrotreatment reactors were carried out, validating the results with a drained bed reactor (TBR), a commercial CoMo/γ-Al2O3 catalyst was used, the material the raw material was Jatropha Curcas L vegetable oil. The operating conditions were temperature 380 ° C, pressure 8 MPag. The kinetic model that was used considered 13 reactions that involve processes of decarboxylation, decarbonization, hydrodeoxygenation and hydrocracking reactions for triolein and tristearin triglycerides. The CFD simulation was carried out in Fluent 18.2 in a transient state and in 3D, considering the standard κ - ε turbulence models, Eulerian multiphase model and porous medium model, it was shown that the countercurrent reactor has less pressure drop than the countercurrent, the conversion the countercurrent reactor has a greater conversion of reactants of 99%, the generation of products from the countercurrent reactor has higher concentrations than the cocurrent reactor, this is because it has more contact areas between phases in the reactor.
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Anand, M., & Sinha, A.K. (2012). Temperature-Dependent Reaction Pathways for the Anomalous Hydrocracking of Triglycerides in the Presence of Sulfided Co–Mo–catalyst. Bioresour Technol, 126, 148–155. https ://doi.org/10.1016/j.biort ech.2012.08.105
Anjani, R. K., Gollakota, M., & Subramanyam, D. (2015). CFD Simulations on the Effect of Catalysts on the Hydrodeoxygenation of Bio-Oil, Royal Society of Chemistry, 5, 41855. https://doi.org/10.1039/C5RA02626A
CPL Press (n.d.). Newbury, UK, Vol. 1. https://www.osti.gov/etdeweb/biblio/20133955
Edward, F. (1983). Chemistry of Catalytic Hydrodeoxygenation, Catalysis Review, 25, UK, 421 - 458. https://doi.org/10.1080/01614948308078052
Elkasabi, Y., & Mullen, C. A. (2014). Hydrodeoxygenation of Fast Pyrolysis Bio – Oils from Various Feedstocks Using Carbon – Supported Catalysts, Fuel Processing Technology, 123, 11-18. https://doi.org/10.1016/j.fuproc.2014.01.039
Guardo, A., & Casanovas, M. (2007). CFD Modeling on External Mass Transfer and Intra- Particle Diffusional Effects on the Supercritical Hydrogenation of Sunflower Oil, Chemical Engineering Science 62, 5054–5061. https://doi.org/10.1016/j.ces.2007.01.080
Gutiérrez, A., & Kaila, R. K. (2009). Hydrodeoxygenation of Guaiacol on Noble Metal Catalysts, Catalysis Today, 147(3-4), 239–246. https://doi.org/10.1016/j.cattod.2008.10.037
Mahfud, F. H. (2007). Hydrotreatment of Fast Pyrolysis Oil Using Heterogeneous Noble Metal Catalysts, PhD Thesis, University of Gronigen : A Handbook, CPL Press, Newbury, UK, vol. 1. https://doi.org/10.1021/ie9006003
Mederos, N. F., Elizalde, M, I., Trejo, Z. F. (2020). Dynamic Modeling and Simulation of Three‑Phase Reactors for Hydrocracking of Vegetable Oils, Reaction Kinetics, Mechanisms and Catalysis 131, 613 – 644. https://doi.org/10.1007/s11144-020-01896-4
Mendoza, C. C., & Vélez, J. F. (2015). CFD Analysis of the Heat Transfer Coefficient During Hydrotreatment of Palm Oil, 08 -12-2015, V Symposium Internacional de Biofábricas, virtual. DOI: 10.1039/c5ra14985a
Mortensen, P. M., Grunwaldt, J. D., Jensen, P. A., Knudsen, K. G., & Jensen, A. D.=. (2011). A review of Catalytic Upgrading of Bio – Oil to Engines Fuels, Applied Catalysis A: general, 407, 1-19. https://doi.org/10.1016/j.apcata.2011.08.046
Muharam, Y., & Putri, A. D. (2019). Phenomenological Model for the Prediction of the Performance of a Slurry Bubble Column Reactor for Green Diesel Production, Journal of physics: Conference series, 1349, 012057. DOI 10.1088/1742-6596/1349/1/012057
Muharam, Y., Nugraha, O. A. (2017). Modelling of a Hydrotreating Reactor to Produce Renewable Diesel from Non-Edible Vegetable Oils, Chemical Engineering Transactions, 56, 1561 – 1566. https://doi.org/10.3303/CET1756261
Oasmaa, A., Meier, D., & Bridgwater, A. (2002). Fast Pyrolysis of Biomass: A Handbook, ANSYS, Inc., (2016), ANSYS Fluent User’s Guide. Canonsburg, PA, USA.
Oyama, S. T. (1996). The Chemistry of Transition Metal Carbides and Nitrides. Blackie Academic and Professional, Springer, Virginia, USA. https://DOI: 10.1007/978-94-009-1565- 7_1
Subramanyam, M. D. (2015), CFD Simulations of Catalytic Hydrodeoxygenation of Bio – Oil Using Pt/Al2O3 in a Fixed Bed Reactor, RSC Advances, 110, 90354 – 90366.
Wildschut, J., & Mahfud, F. H. (2009). Hydrotreatment of Fast Pyrolysis Oil Using Heterogeneous Noble - Metal Catalysts, Ind. Eng. Chem. Res., 48(23), 1324– 1334. https://doi.org/10.1021/ie9006003
Wildschut, J., & Melian – Cabrera, I. (2010). Catalyst Studies on the Hydrotreatment of Fast Pyrolysis oil, Applied Catalysis B: Environmental, 99(1 -2), 298 – 306. https://doi.org/10.1016/j.apcatb.2010.06.036
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