A KINETIC STUDY ON THE OXIDATION OF MALIC ACID BY CHLORAMINES - T IN MICELLAR SYSTEM

Authors

  • Smt. Manmeet Kaur Makkad Department of Chemistry, Government Madhav Science P.G. College, Ujjain (M.P.), India

DOI:

https://doi.org/10.29121/ijetmr.v4.i12.2017.586

Keywords:

Kinetic Study, Oxidation, Micellar System, Chloramines

Abstract

The oxidation of malic acid by chloramine –T with the presence of cationic surfactant e.g.,
cetyltrimethyl ammonium bromide (CTAB) in acetic acid medium has been studied. The
reaction shows first order with respect to [CAT] and fractional order with respect to
[Substrate]. The reaction rate decraeses with increase in concentration of acetic acid. The
reaction has retarding effect on the addition on product (P-Toluene Sulphonamide). The
activation parameters evaluation has been on the basis of temperature variations studied.
A literature survey reveals that very limited information have been available on the oxidation
of malic acid by CAT in micellar system1. This has prompted us to undertake a kinetic study
on this reaction.

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References

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Hartley,G.S., Quart Rev. Chemistry .Sec.Q.PP 153- 183 (1948)

Amis.E.S, “Solvent effect on reaction rate and Mechanism Academic Press, New York (1960)

Mukherji.J and Benerji.K.K , Organic Chemistry,46,2323 (1981) DOI: https://doi.org/10.1021/jo00324a022

Fiegi.F., Spot test in organic Analysis” Elsevier Publishing Co. Amsterdam.331(1956)

Mitchell.J. (Jr), “Organic Analysis” Vol-1, Inter science Publishers, Inc, New York 279 (1953).

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Published

2017-12-31

How to Cite

Makkad, S. M. K. (2017). A KINETIC STUDY ON THE OXIDATION OF MALIC ACID BY CHLORAMINES - T IN MICELLAR SYSTEM. International Journal of Engineering Technologies and Management Research, 4(12), 19–23. https://doi.org/10.29121/ijetmr.v4.i12.2017.586