KINETICS OF OXIDATION OF UNSATURATED ACID BY THALLIUM(III) IN AQUEOUS ACETIC ACID AND MICELLAR MEDIUM
DOI:
https://doi.org/10.29121/granthaalayah.v13.i2.2025.5990Keywords:
Crotonic Acid, Thallium(III), Perchlorate, Cetyltrimethylammonium Bromide (CTAB), Oxidation, StoichiometryAbstract [English]
The oxidation of α-crotonic acid by thallium (III) perchlorate proceeds by a mechanism approach involving direct two-electron transfer with lack of free radical intervention from substrate to the oxidant via an intermediate complex. The stoichiometry (1:1) of the reaction followed by its decomposition in a rate-determining step to product acetaldehyde. The orders in oxidant and acid were found to be unity, whereas solvent, micellar (CTAB) exhibited fraction-order kinetics. The activation parameters were also discussed.
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Agnihotri, M., & Tiwari, S. (2021). Int. J. Theor. & Appl. Sciences, 13(2), 12-16.
Banerji, K. K. (1972). Journal of the Indian Chemical Society, 49, 1097.
Bhuvaneshwari, D. S., & Elango, K. P. (2006). International Journal of Chemical Kinetics, 38, 657-665. https://doi.org/10.1002/kin.20199
Hemkar, S., Riya, S., Khandelwal, C., & Sharma, P. D. (2013). American Journal of Physical Chemistry, 2(5), 73-79.
Josh, G. K., Katre, Y. R., & Singh, A. K. (2006). Journal of Surfactants and Detergents, 9, 231-235. https://doi.org/10.1007/s11743-006-5002-3
Lene, G., Fabian, I., & Poe, A. I. (2005). New Journal of Chemistry, 29, 759-760.
Mahesh, R. T., Belakki, M. B., & Nandibewoor, S. T. (2004). Catalysis Letters, 97, 91-98. https://doi.org/10.1023/B:CATL.0000034293.78427.8d
Prajapati, A., Dwivedi, A. P., & Parihar, S. S. (2019). International Journal of Chemistry Science, 3(4), 9-11.
Ramachandrappa, R., Puttaswamy, Mayanna, S. M., & Made Gowda, N. B. (1998). International Journal of Chemical Kinetics, 30(6), 407-414. https://doi.org/10.1002/(SICI)1097-4601(1998)30:6<407::AD-KIN2>3.0.CO;2-W
Shah, N. H., Dar, N. A., Farhad, & Singh, S. P. (2022). Chemical Society Transactions, 11(2-4), 26-32.
Shrivastava, A., & Neelam. (2015). International Journal of Applied Research, 10, 380-384.
Singh, N., & Swami, M. N. (2022). International Journal of Theoretical & Applied Sciences, 14(91), 53-56.
Singh, R., & Dubey, V. (2023). International Journal of Science Development and Research, 8(1), 1036-1039.
Swain, C. G., Swain, M. S., Powel, A. L., & Alunni, S. (1983). Journal of the American Chemical Society, 105, 502. https://doi.org/10.1021/ja00341a033
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